Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses

Ramkrishna Mahto; Ghizal Firdous Ansari; Sukhdev Bairagi; Ashok Kumar Sharma

doi:doi:10.11648/j.jmpt.20220802.11

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Studies of Physical and Optical Behavior of Er^³⁺/Yb^³⁺ Co-doped Titanium Tellurite Glasses

Ramkrishna Mahto, Ghizal Firdous Ansari, Sukhdev Bairagi, Ashok Kumar Sharma

Published in Journal of Photonic Materials and Technology (Volume 8, Issue 2)

Received: 27 October 2022 Accepted: 10 November 2022 Published: 23 November 2022

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Abstract

The Er₂O₃-Yb₂O₃ codoped TeO₂-TiO₂-Na₂O-glasses have batch compositions of (70-x-y) %TeO₂-20%. TiO₂-10% Na₂O-x% Er₂O₃-y% Yb₂O₃ have been prepared successfully by using the conventional melt quench technique, where (x, y) are (0, 1, 1) and (0, 1, 2). Differential scanning calorimetry (DSC) is used to measure the glass transition temperature of synthesized samples. X-ray Diffraction studies were made on these glass samples at room temperature. The amorphous nature of the prepared glass samples was confirmed from the XRD patterns. The density of prepared glass samples was determined by using the fluid displacement method, which is based on the Archimedes principle. Other physical properties of synthesized glass sample such as molar volume (V_m), titanium ion concentration (N), Polaron radius (R_p), inter nuclear distance (R_i), molar refractivity (R_m), Oxygen Packing density (OPD) and field strength (χ) were calculated. The UV-Visible absorption characterizations of synthesized glasses with varying Er₂O₃/Yb₂O₃ doping percentages were carried out in the 400–1000 nm range. Glasses optical characteristics, including their absorption coefficient (α), refractive index, the band gap energies for both direct and indirect possible transitions and the Urbach energies (Eu) have been studied from the absorption spectra. The impact of Er₂O₃/Yb₂O₃ and effect of thickness on optical characteristic is observed.

Published in	Journal of Photonic Materials and Technology (Volume 8, Issue 2)
DOI	10.11648/j.jmpt.20220802.11
Page(s)	11-16
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Rare Earth Doped Glass, X- Ray Diffraction, Optical Properties, Absorption Spectra, Urbach Energy

References

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APA Style

Ramkrishna Mahto, Ghizal Firdous Ansari, Sukhdev Bairagi, Ashok Kumar Sharma. (2022). Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses. Journal of Photonic Materials and Technology, 8(2), 11-16. https://doi.org/10.11648/j.jmpt.20220802.11

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ACS Style

Ramkrishna Mahto; Ghizal Firdous Ansari; Sukhdev Bairagi; Ashok Kumar Sharma. Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses. J. Photonic Mater. Technol. 2022, 8(2), 11-16. doi: 10.11648/j.jmpt.20220802.11

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AMA Style

Ramkrishna Mahto, Ghizal Firdous Ansari, Sukhdev Bairagi, Ashok Kumar Sharma. Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses. J Photonic Mater Technol. 2022;8(2):11-16. doi: 10.11648/j.jmpt.20220802.11

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@article{10.11648/j.jmpt.20220802.11,
  author = {Ramkrishna Mahto and Ghizal Firdous Ansari and Sukhdev Bairagi and Ashok Kumar Sharma},
  title = {Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses},
  journal = {Journal of Photonic Materials and Technology},
  volume = {8},
  number = {2},
  pages = {11-16},
  doi = {10.11648/j.jmpt.20220802.11},
  url = {https://doi.org/10.11648/j.jmpt.20220802.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jmpt.20220802.11},
  abstract = {The Er2O3-Yb2O3 codoped TeO2-TiO2-Na2O-glasses have batch compositions of (70-x-y) %TeO2-20%. TiO2-10% Na2O-x% Er2O3-y% Yb2O3 have been prepared successfully by using the conventional melt quench technique, where (x, y) are (0, 1, 1) and (0, 1, 2). Differential scanning calorimetry (DSC) is used to measure the glass transition temperature of synthesized samples. X-ray Diffraction studies were made on these glass samples at room temperature. The amorphous nature of the prepared glass samples was confirmed from the XRD patterns. The density of prepared glass samples was determined by using the fluid displacement method, which is based on the Archimedes principle. Other physical properties of synthesized glass sample such as molar volume (Vm), titanium ion concentration (N), Polaron radius (Rp), inter nuclear distance (Ri), molar refractivity (Rm), Oxygen Packing density (OPD) and field strength (χ) were calculated. The UV-Visible absorption characterizations of synthesized glasses with varying Er2O3/Yb2O3 doping percentages were carried out in the 400–1000 nm range. Glasses optical characteristics, including their absorption coefficient (α), refractive index, the band gap energies for both direct and indirect possible transitions and the Urbach energies (Eu) have been studied from the absorption spectra. The impact of Er2O3/Yb2O3 and effect of thickness on optical characteristic is observed.},
 year = {2022}
}

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TY  - JOUR
T1  - Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses
AU  - Ramkrishna Mahto
AU  - Ghizal Firdous Ansari
AU  - Sukhdev Bairagi
AU  - Ashok Kumar Sharma
Y1  - 2022/11/23
PY  - 2022
N1  - https://doi.org/10.11648/j.jmpt.20220802.11
DO  - 10.11648/j.jmpt.20220802.11
T2  - Journal of Photonic Materials and Technology
JF  - Journal of Photonic Materials and Technology
JO  - Journal of Photonic Materials and Technology
SP  - 11
EP  - 16
PB  - Science Publishing Group
SN  - 2469-8431
UR  - https://doi.org/10.11648/j.jmpt.20220802.11
AB  - The Er2O3-Yb2O3 codoped TeO2-TiO2-Na2O-glasses have batch compositions of (70-x-y) %TeO2-20%. TiO2-10% Na2O-x% Er2O3-y% Yb2O3 have been prepared successfully by using the conventional melt quench technique, where (x, y) are (0, 1, 1) and (0, 1, 2). Differential scanning calorimetry (DSC) is used to measure the glass transition temperature of synthesized samples. X-ray Diffraction studies were made on these glass samples at room temperature. The amorphous nature of the prepared glass samples was confirmed from the XRD patterns. The density of prepared glass samples was determined by using the fluid displacement method, which is based on the Archimedes principle. Other physical properties of synthesized glass sample such as molar volume (Vm), titanium ion concentration (N), Polaron radius (Rp), inter nuclear distance (Ri), molar refractivity (Rm), Oxygen Packing density (OPD) and field strength (χ) were calculated. The UV-Visible absorption characterizations of synthesized glasses with varying Er2O3/Yb2O3 doping percentages were carried out in the 400–1000 nm range. Glasses optical characteristics, including their absorption coefficient (α), refractive index, the band gap energies for both direct and indirect possible transitions and the Urbach energies (Eu) have been studied from the absorption spectra. The impact of Er2O3/Yb2O3 and effect of thickness on optical characteristic is observed.
VL  - 8
IS  - 2
ER  -

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Author Information

Ramkrishna Mahto

Physics Department, Madhyanchal Professional University, Bhopal, India
Ghizal Firdous Ansari

Physics Department, Madhyanchal Professional University, Bhopal, India
Sukhdev Bairagi

Physics Department, Madhyanchal Professional University, Bhopal, India
Ashok Kumar Sharma

Physics Department, Madhyanchal Professional University, Bhopal, India

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APA Style

Ramkrishna Mahto, Ghizal Firdous Ansari, Sukhdev Bairagi, Ashok Kumar Sharma. (2022). Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses. Journal of Photonic Materials and Technology, 8(2), 11-16. https://doi.org/10.11648/j.jmpt.20220802.11

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ACS Style

Ramkrishna Mahto; Ghizal Firdous Ansari; Sukhdev Bairagi; Ashok Kumar Sharma. Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses. J. Photonic Mater. Technol. 2022, 8(2), 11-16. doi: 10.11648/j.jmpt.20220802.11

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AMA Style

Ramkrishna Mahto, Ghizal Firdous Ansari, Sukhdev Bairagi, Ashok Kumar Sharma. Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses. J Photonic Mater Technol. 2022;8(2):11-16. doi: 10.11648/j.jmpt.20220802.11

Copy | Download

@article{10.11648/j.jmpt.20220802.11,
  author = {Ramkrishna Mahto and Ghizal Firdous Ansari and Sukhdev Bairagi and Ashok Kumar Sharma},
  title = {Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses},
  journal = {Journal of Photonic Materials and Technology},
  volume = {8},
  number = {2},
  pages = {11-16},
  doi = {10.11648/j.jmpt.20220802.11},
  url = {https://doi.org/10.11648/j.jmpt.20220802.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jmpt.20220802.11},
  abstract = {The Er2O3-Yb2O3 codoped TeO2-TiO2-Na2O-glasses have batch compositions of (70-x-y) %TeO2-20%. TiO2-10% Na2O-x% Er2O3-y% Yb2O3 have been prepared successfully by using the conventional melt quench technique, where (x, y) are (0, 1, 1) and (0, 1, 2). Differential scanning calorimetry (DSC) is used to measure the glass transition temperature of synthesized samples. X-ray Diffraction studies were made on these glass samples at room temperature. The amorphous nature of the prepared glass samples was confirmed from the XRD patterns. The density of prepared glass samples was determined by using the fluid displacement method, which is based on the Archimedes principle. Other physical properties of synthesized glass sample such as molar volume (Vm), titanium ion concentration (N), Polaron radius (Rp), inter nuclear distance (Ri), molar refractivity (Rm), Oxygen Packing density (OPD) and field strength (χ) were calculated. The UV-Visible absorption characterizations of synthesized glasses with varying Er2O3/Yb2O3 doping percentages were carried out in the 400–1000 nm range. Glasses optical characteristics, including their absorption coefficient (α), refractive index, the band gap energies for both direct and indirect possible transitions and the Urbach energies (Eu) have been studied from the absorption spectra. The impact of Er2O3/Yb2O3 and effect of thickness on optical characteristic is observed.},
 year = {2022}
}

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TY  - JOUR
T1  - Studies of Physical and Optical Behavior of Er3+/Yb3+ Co-doped Titanium Tellurite Glasses
AU  - Ramkrishna Mahto
AU  - Ghizal Firdous Ansari
AU  - Sukhdev Bairagi
AU  - Ashok Kumar Sharma
Y1  - 2022/11/23
PY  - 2022
N1  - https://doi.org/10.11648/j.jmpt.20220802.11
DO  - 10.11648/j.jmpt.20220802.11
T2  - Journal of Photonic Materials and Technology
JF  - Journal of Photonic Materials and Technology
JO  - Journal of Photonic Materials and Technology
SP  - 11
EP  - 16
PB  - Science Publishing Group
SN  - 2469-8431
UR  - https://doi.org/10.11648/j.jmpt.20220802.11
AB  - The Er2O3-Yb2O3 codoped TeO2-TiO2-Na2O-glasses have batch compositions of (70-x-y) %TeO2-20%. TiO2-10% Na2O-x% Er2O3-y% Yb2O3 have been prepared successfully by using the conventional melt quench technique, where (x, y) are (0, 1, 1) and (0, 1, 2). Differential scanning calorimetry (DSC) is used to measure the glass transition temperature of synthesized samples. X-ray Diffraction studies were made on these glass samples at room temperature. The amorphous nature of the prepared glass samples was confirmed from the XRD patterns. The density of prepared glass samples was determined by using the fluid displacement method, which is based on the Archimedes principle. Other physical properties of synthesized glass sample such as molar volume (Vm), titanium ion concentration (N), Polaron radius (Rp), inter nuclear distance (Ri), molar refractivity (Rm), Oxygen Packing density (OPD) and field strength (χ) were calculated. The UV-Visible absorption characterizations of synthesized glasses with varying Er2O3/Yb2O3 doping percentages were carried out in the 400–1000 nm range. Glasses optical characteristics, including their absorption coefficient (α), refractive index, the band gap energies for both direct and indirect possible transitions and the Urbach energies (Eu) have been studied from the absorption spectra. The impact of Er2O3/Yb2O3 and effect of thickness on optical characteristic is observed.
VL  - 8
IS  - 2
ER  -

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