Volume 5, Issue 2, December 2019, Page: 32-37
Study of the Optical Properties of Isonitrosoacetophenone (C8H7NO2) Using UV-Vis Spectroscopy
Salma Fath Alrahman Ahmed, Faculty of Radiobiological and Imaging Sciences, Alzaeim Al-Azhari University, Bahry, Sudan
Khalid Mohamed Haroun, Faculty of Radiobiological and Imaging Sciences, Alzaeim Al-Azhari University, Bahry, Sudan
Adam Mohammed Adam Bakheet, Department of Physics & Astronomy, Faculty of Science, University of Gezira, Madani, Sudan
Yousif Hassan Alsheikh, Department of Applied Physics & Mathematics, Omdurman Ahlia University, Omdurman, Sudan;Faculty of Basic Studies, The Future University, Khartoum, Sudan
Abdalsakhi Suliman, Faculty of Science and Technology-Physics (Laser) Department, AlNeenlen University, Khartoum, Sudan
Received: Oct. 25, 2019;       Accepted: Dec. 16, 2019;       Published: Jan. 6, 2020
DOI: 10.11648/j.jmpt.20190502.12      View  528      Downloads  82
Abstract
In this work, the optical properties (absorption, absorption coefficient, refractive index, band- gap energy, extension coefficient, and reflection) of the five samples of isonitrosoacetophenone (C8H7NO2) was studied using Uv-Vis spectroscopy. The C8H7NO2 was dissolved in different amounts of (0.5, 1, 1.5, and 2) ml of distilled water. The effect of concentration on the optical properties of C8H7NO2 was investigated experimentally and it was shown that the different values of the calculated optical properties are clearly affected by the concentrations of the C8H7NO2 compound. In addition, when the isonitrosoacetophenone is mixed with 2.0 ml of water the absorbance rate of the pure isonitrosoacetophenone was shown to be decreased from 2.7×10-4 (a. u.) at 278 nm to 1×10-4 (a. u.) at the same wavelength. Furthermore, the transmission of C8H7NO2 was shifted towards the shorter wavelength as the concentration of water is increased, which is starts from ~346 nm for pure isonitrosoacetophenone and decreased to ~ 300 nm when mixed with 2.0 ml of water. The important finding of this work was that the compound C8H7NO2 is opaque (non-transmittance) material from the wavelength of 220 to 300 nm which corresponds to the UV portion of the electromagnetic spectrum and this suggests more study in this area.
Keywords
Isonitrosoacetophenone, Optical Properties, Uv-vis Spectroscopy, Band-gap Energy
To cite this article
Salma Fath Alrahman Ahmed, Khalid Mohamed Haroun, Adam Mohammed Adam Bakheet, Yousif Hassan Alsheikh, Abdalsakhi Suliman, Study of the Optical Properties of Isonitrosoacetophenone (C8H7NO2) Using UV-Vis Spectroscopy, Journal of Photonic Materials and Technology. Vol. 5, No. 2, 2019, pp. 32-37. doi: 10.11648/j.jmpt.20190502.12
Copyright
Copyright © 2019 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Reference
[1]
Yunus Kaya, Veysel T. Yilmaz and Orhan Buyukgungor (2016), Synthesis, Spectroscopic, Structural and Quantum Chemical Studies of a New Imine Oxime and Its Palladium(II) Complex: Hydrolysis Mechanism, Journal of Molecules. 2016 Jan; volume 21 (1): 52, doi: 10.3390/molecules21010052.
[2]
Ayşin Zülfikaroğlu, Hümeyra Batı and Necmi Dege (2018), A theoretical and experimental study on isonitrosoacetophenone nicotinoyl hydrazone: Crystal structure, spectroscopic properties, NBO, NPA and NLMO analyses and the investigation of interaction with some transition metals, Journal of Molecular Structure 1162 • February 2018.
[3]
Sandhyamayee Sahu et al., (2008), Deoximation of keto- And aldoximes to carbonyl compounds, Indian Journal of Chemistry Section B volume 47, issue (2), pp. 259-271.
[4]
Jagdish V. Bharad Balaji Madje, and Milind Ubale (2013), Quantitative Regeneration of Carbonyl Compounds from Oximes under Microwave Irradiations using N-bromosuccinimide, International Journal of Recent Trends in Science And Technology, ISSN 2277-2812 E-ISSN 2249-8109, Special Issue, ACTRA-INDIA, Sept. 2013 pp 21-22.
[5]
Selvaganapathy M and Raman Natarajan (2016), Pharmacological Activity of a Few Transition Metal Complexes: A Short Review, J Chem Biol Ther 2016, Vol 1 (2): 108, DOI: 10.4172/2572-0406.1000108.
[6]
Yunus Kaya and Veysel T. Yilmaz (2014), Theoretical study of hydrolysis of an imine oxime in aqueous solution and crystal structure and spectroscopic characterization of a platinum(II) complex containing the hydrolysis product, Structural Chemistry, volume 25, pp. 231-238.
[7]
Maral Aminpour, Carlo Montemagno, and Jack A. Tuszynski, (2019), An Overview of Molecular Modeling for Drug Discovery with Specific Illustrative Examples of Applications, Journal of Molecules, volume 24 (9): 1693, doi: 10.3390/molecules24091693.
[8]
UV-mini 1240 supplied by shimadzu, online data sheet, available on https://shimadzu.com.au/uv-1240, visited 12/11/2018.
[9]
Waleed Bedeawy Salih (2010), The Study of Optical Properties of Thin films Cd1−xMgxS Prepared by Chemical Spry Pyrolysis Technique, J. of university of anbar for pure science: Vol. 4: NO. 2: 2010.
[10]
Waleed. B. Abdala, Rawia Abd Elgani, Mubarak Dirar Abd, Abdalskhi. S. M. H & Sawsan Ahmed Elhouri Ahmed- OPTICAL PRORATES OF WASTE PETROLEUM COKE POWDER (WPCP) TREATMENT BY ACIDS - GLOBAL JOURNAL OF ENGINEERING SCIENCE AND RESEARCHES - [Waleed, 5 (10): October 2018] ISSN 2348 – 8034 DOI- 10.5281/zenodo.1445500 Impact Factor- 5.070.
[11]
Zohal E. M. Ebnouf, Mubarak Dirar Abdallah, M. H. M. Hilo, Ahmed H. Alfaki, Abdalsakhi S M. H & Sawsan Ahmed Elhouri Ahmed - The Effect Of Changing Al2O3 Concentrations And Nano Crystal Size On (Zno) X (Al2O3) 1-X Thin Films Conductivity And Imaginary Electric Permittivity - IJISET - International Journal of Innovative Science, Engineering & Technology, Vol. 6 Issue 2, February 2019 ISSN (Online) 2348 – 7968 www.ijiset.com.
[12]
Greene LE, Law M, Tan DH, Montano M, Goldberger J, Somorjai G, et al. General route to vertical ZnO nanowire arrays using textured ZnO seeds. Nano Lett. 2005; 5: 1231-6.
[13]
Aldesogi Omer Hamed, Nadir A. Mustafa, Abdalsakhi. S. Mohammd, Montasir Salman Elfadel Tyfor, Effect of difference concentrations of Al on the optical properties of AZO thin films - IOSR Journal of Applied Physics (IOSR-JAP) e-ISSN: 2278-4861. Volume 8, Issue 6 Ver. I (Nov. - Dec. 2016), PP 40-45 www.iosrjournals.org.
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